不锈钢电弧铆焊焊点组织及力学性能

采用电弧铆焊的方法对3 mm+5 mm厚的0Cr18Ni9不锈钢钢板采用搭接形式实现连接. 通过优化焊接电流及其作用时间的参数匹配，以期得到最佳的焊点显微组织和力学性能. 采用X射线检测焊点缺陷的存在，使用金相显微镜研究焊点熔深和熔核尺寸的变化，使用电子万能试验机测试焊点的抗剪力. 结果表明，电弧铆焊焊点呈蘑菇状，与基体圆滑过渡，成形良好，无气孔、裂纹等宏观缺陷. 随着第一段和第二段焊接电流的增大，焊点的熔深和熔核尺寸，及焊点抗剪力随之增大. 优化的工艺参数下，熔深尺寸可达4.07 mm，熔核尺寸可达7.73 mm，抗剪力可达23.654 kN，满足生产需求.     

Detailed Insight into the Interaction of Bicyclic Somatostatin Analogue with Cu(II) Ions

Somatostatin analogues are useful pharmaceuticals in peptide receptor radionuclide therapy. In previous studies, we analyzed a new bicyclic somatostatin analogue (BCS) in connection with Cu(II) ions. Two characteristic sites were present in the peptide chain: the receptor- and the metal-binding site. We have already shown that this ligand can form very stable imidazole complexes with the metal ion. In this work, our aim was to characterize the intramolecular interaction that occurs in the peptide molecule. Therefore, we analyzed the coordination abilities of two cyclic ligands, i.e., P1 only with the metal binding site and P2 with both sites, but without the disulfide bond. Furthermore, we used magnetic circular dichroism (MCD) spectroscopy to better understand the coordination process. We applied this method to analyze spectra of P1, P2, and BCS, which we have described previously. Additionally, we analyzed the MCD spectra of P3 ligand, which has only the receptor binding site in its structure. We have unequivocally shown that the presence of the Phe-Trp-Lys-Thr motif and the disulfide bond significantly increases the metal binding efficiency.     

蓝宝石晶体掏棒机内冷式刀柄辅具结构研究

因蓝宝石晶体硬度为莫氏9级,仅次于最硬白金刚石,蓝宝石晶体掏棒加工中会产生很高的切削热量,筒刀和晶体必须进行筒刀内部和外部同时强力冷却,才能保证掏棒加工的稳定性和晶棒质量。所以蓝宝石晶体掏棒加工中要解决的关键技术问题之一,是内冷式刀柄辅具结构的研究、设计、试制、改进和联机使用。     

山西沁水盆地3号煤层水平井施工技术探究

近年来,建设单位在山西沁水盆地郑庄区块部署较多的煤层气水平井,目的层为3号、15号煤层气储层,施工中受技术及地层因素的影响,多次出现煤层顶板坍塌、卡钻甚至埋钻事故,严重地影响了钻井效率,造成极大的经济损失。针对施工中存在的技术问题,采用无线随钻仪器双伽马技术来控制施工轨迹沿煤层夹矸钻进的方法来指导施工,通过对仪器电信号数据的充分辨识和利用,基本摸清了煤层赋存形态及结构,控制了施工轨迹;采用多种方法进行通井、遇阻划眼,确保井眼圆滑通畅。取得了快速、安全、高效的施工效果,达到了顺利完井的目的,解决了该区块水平井施工的技术难题,对该区水平井的施工具有指导意义。     

矿用减速器太阳轮齿面PVD表面改性的研究

针对矿用减速器太阳轮接触强度最小安全系数通常小于1.25,即可靠度不理想的问题,对太阳轮常用材料17CrNiMo6进行物理气相沉积(PVD)处理。将其表面附着TiN涂层、TiC复合层,并对这2种涂层进行厚度、硬度、密着力、EDS分析。研究表明:齿面进行PVD表面改性虽然具有粗糙度良好、涂层均匀以及密着力好等优点,但其硬度有所降低。     

EBZ160掘进机截割减速机打齿分析及改进

EBZ160掘进机用于煤矿井下巷道采掘,时常发生截割减速机打齿现象。主要分析造成截割减速机打齿的原因,提出对输入轴和太阳轮进行改进设计和合理选择齿轮材质,彻底解决因截割减速机打齿导致齿轮箱损坏的问题,并成功推广应用。     

国内齿辊式破碎机常用齿板材料的组织和性能

通过组织观察、力学性能检测和磨损实验,对比研究了洗煤生产过程中齿辊式破碎机的国内4种常用齿板材料的组织和性能。结果表明,进口齿板材料的组织由板条马氏体和6.13%的残余奥氏体组成;高锰钢齿板的组织为单相奥氏体组织;ZG32CrMnSiNi2Mo齿板的组织由贝氏体铁素体板条和13.18%残余奥氏体组成;ZG22CrMnSiNiMo齿板为粒状贝氏体组织,组织中条型M-A岛比例较多,残余奥氏体量为14.9%。940℃淬火+200℃回火后,进口齿板材料具有最优的综合性能,硬度和冲击韧性分别为44.1 HRC和34.5 J;高锰钢齿板水韧处理后平均硬度为216.5 HB,冲击韧度为113.8 J;ZG32CrMnSiNi2Mo齿板900~940℃正火处理后,冲击韧度值略低于进口齿板的供货状态,但硬度高于进口齿板;960~1000℃正火处理后,ZG22CrMnSiNiMo齿板硬度略低于进口齿板材料,冲击韧度略高于进口齿板材料。选取进口齿板材料供货状态为标准,高锰钢齿板材料的相对耐磨性较低,仅为0.76;ZG32CrMnSiNi2Mo齿板材料经900~980℃正火处理后,耐磨性能较好,相对耐磨性为1.19~1.23;ZG22CrMnSiNiMo齿板材料经920~1000℃正火处理,耐磨性能介于进口齿板材料和ZG32CrMnSiNi2Mo齿板材料之间,相对耐磨性为1.10~1.13。     

Study on stress and deformation of keyhole gas tungsten arc-welded joints

Keyhole gas tungsten arc welding(K-TIG)of Q345 low alloy steel plates was simulated by using SYSWELD software.The temperature field of the K-TIG welding process was simulated with three different combined heat sources and was compared with the weld profile that was obtained experimentally.The temperature field that was obtained by a combination of a double ellipsoid heat source on the upper half and a three-dimensional Gauss heat source on the lower half was similar to the real situation.The effects of plate thickness,gap and welding speed on the deformation and stress of the K-TIG welded joints were investigated by K-TIG welding numerical simulation.A reduction in the thickness of the weld plates reduced the z-direction deformation and transverse residual stress;an appropriate gap reduced the residual stress and an increase in the welding speed reduced deformation after welding,but did not help to control the residual stress after welding.     

In situ direct growth of flower-like hierarchical architecture of CoNi-layered double hydroxide on Ni foam as an efficient self-supported oxygen evolution electrocatalyst

Exploring economical, efficient and robust electrocatalysts toward the oxygen evolution reaction (OER) is one of the key issues in water splitting technology. Nanostructure engineering of electrocatalysts and hybridizing active species with a conductive support represent powerful strategies to enhance the electrocatalytic performance. Herein, we report a facile one-step solvothermal method to directly grow 3D CoNi-layered double hydroxide (LDH) flower-like architectures onto porous and conductive Ni foam (NF) substrate (denoted as CoNi-LDH(2:1)@NF hereafter). The flower-like hierarchical architecture of CoNi-LDHs with open configurations endows CoNi-LDH microflowers with sufficient accessible active sites and efficient mass diffusion paths. Moreover, the in situ direct growth manner ensures an intimate contact between the electroactive CoNi-LDHs and NF substrate and thus the charge transfer resistance is reduced. Consequently, the as-formed self-supported and binder-free electrode of CoNi-LDH(2:1)@NF exhibits an outstanding OER performance with a small overpotential of 283 mV at a relatively large current density of 50 mA cm⁻² and a remarkable long-term electrochemical durability in 0.1 M KOH solution, holding great promise in practical scale-up water electrolysis. The present study may open a new avenue to design and fabricate cost-effective and high-efficiency electrocatalysts for energy conversion applications.     

Study of a new type of self‐centering beam‐column joint in steel frame structures

A new type of self‐centering beam‐column joint with installed steel arc plates is proposed in this study. First, mechanical behavior of the self‐centering joint using prestressed steel strands to provide the centering force is theoretically analyzed in detail, followed by experimental validation. New joints with different arc plate parameters are designed and tested under cyclic loading. Test results show that the hysteretic curve of the new joint exhibits typical characteristic of self‐centering capacity. By parametric analysis of five design parameters of the arc plate, it is found that vector height has the greatest influence on the joint's moment‐rotation skeleton curve, which is consistent with experimental findings. A simplified model of the joint is built in OpenSees to simulate its hysteretic behavior, which agrees well with the tested results. To demonstrate the effectiveness of the new joint to improve the seismic performance of the overall structure, a series of nonlinear time history analysis on a steel frame structure with the new joint under earthquakes are conducted, which show that the joint is particularly effective in reducing the residual interstory drift response.